| Date | Match | Result | Score | Competition |
|---|---|---|---|---|
| 29 Sep 1999 | Barcelona v Arsenal | D | 1-1 | UEFA Champions League |
| 19 Oct 1999 | Arsenal v Barcelona | L | 2-4 | UEFA Champions League |
| 17 May 2006 | Arsenal v Barcelona | L | 1-2 | UEFA Champions League |
| 31 Mar 2010 | Arsenal v Barcelona | D | 2-2 | UEFA Champions League |
| 06 Apr 2010 | Barcelona v Arsenal | L | 4-1 | UEFA Champions League |
| 16 Feb 2011 | Arsenal v Barcelona | W | 2-1 | UEFA Champions League |
| 08 Mar 2011 | Barcelona v Arsenal | L | 3-1 | UEFA Champions League |
| 23 Feb 2016 | Arsenal v Barcelona | L | 0-2 | UEFA Champions League |
| 16 Mar 2016 | Barcelona v Arsenal | UEFA Champions League |
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